Evaluation and characterization of Pd-Ag composite membrane fabricated by surfactant induced electroless plating (SIEP) for hydrogen separation

M. M. Rahman; M. S. Islam; M. A. Rahman; H. Tun; V. Deshmane; T. Hossain; S. Ilias

doi:10.1080/01496395.2019.1576734

Evaluation and characterization of Pd-Ag composite membrane fabricated by surfactant induced electroless plating (SIEP) for hydrogen separation

M. M. Rahman, M. S. Islam, M. A. Rahman, H. Tun, V. Deshmane, T. Hossain, S. Ilias

Industrial and systems engineering with North Carolina A&T State University

Research output: Contribution to journal › Article › peer-review

Abstract

Dense Pd-Ag/MPSS composite membranes were fabricated on macroporous stainless steel substrate (MPSS) by novel surfactant induced electroless plating (SIEP) process. SIEP was effective in synthesizing dense and thinner Pd-Ag films on MPSS with shorter deposition time in presence of cationic DTAB. SIEP membranes showed 3–8 times higher H₂ permeance compared to that of conventional EP membranes. The SEM, XRD, and EDS studies confirmed the formation of Pd-Ag alloy and no diffusion of MPSS substrate metal components into the Pd-Ag film. The Pd-Ag membrane (15 μm thickness) was tested for long-term stability under thermal cycling (623–723-623 K) up to 42 days.

Original language	English
Pages (from-to)	2084-2097
Number of pages	14
Journal	Separation Science and Technology (Philadelphia)
Volume	54
Issue number	13
DOIs	https://doi.org/10.1080/01496395.2019.1576734
State	Published - Sep 2 2019
Externally published	Yes

Keywords

H separation
H/N selectivity
Pd-Ag membrane
SIEP
thermal stability

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10.1080/01496395.2019.1576734

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title = "Evaluation and characterization of Pd-Ag composite membrane fabricated by surfactant induced electroless plating (SIEP) for hydrogen separation",

abstract = "Dense Pd-Ag/MPSS composite membranes were fabricated on macroporous stainless steel substrate (MPSS) by novel surfactant induced electroless plating (SIEP) process. SIEP was effective in synthesizing dense and thinner Pd-Ag films on MPSS with shorter deposition time in presence of cationic DTAB. SIEP membranes showed 3–8 times higher H2 permeance compared to that of conventional EP membranes. The SEM, XRD, and EDS studies confirmed the formation of Pd-Ag alloy and no diffusion of MPSS substrate metal components into the Pd-Ag film. The Pd-Ag membrane (15 μm thickness) was tested for long-term stability under thermal cycling (623–723-623 K) up to 42 days.",

keywords = "H separation, H/N selectivity, Pd-Ag membrane, SIEP, thermal stability",

author = "Rahman, \{M. M.\} and Islam, \{M. S.\} and Rahman, \{M. A.\} and H. Tun and V. Deshmane and T. Hossain and S. Ilias",

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doi = "10.1080/01496395.2019.1576734",

language = "English",

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TY - JOUR

T1 - Evaluation and characterization of Pd-Ag composite membrane fabricated by surfactant induced electroless plating (SIEP) for hydrogen separation

AU - Rahman, M. M.

AU - Islam, M. S.

AU - Rahman, M. A.

AU - Tun, H.

AU - Deshmane, V.

AU - Hossain, T.

AU - Ilias, S.

PY - 2019/9/2

Y1 - 2019/9/2

N2 - Dense Pd-Ag/MPSS composite membranes were fabricated on macroporous stainless steel substrate (MPSS) by novel surfactant induced electroless plating (SIEP) process. SIEP was effective in synthesizing dense and thinner Pd-Ag films on MPSS with shorter deposition time in presence of cationic DTAB. SIEP membranes showed 3–8 times higher H2 permeance compared to that of conventional EP membranes. The SEM, XRD, and EDS studies confirmed the formation of Pd-Ag alloy and no diffusion of MPSS substrate metal components into the Pd-Ag film. The Pd-Ag membrane (15 μm thickness) was tested for long-term stability under thermal cycling (623–723-623 K) up to 42 days.

AB - Dense Pd-Ag/MPSS composite membranes were fabricated on macroporous stainless steel substrate (MPSS) by novel surfactant induced electroless plating (SIEP) process. SIEP was effective in synthesizing dense and thinner Pd-Ag films on MPSS with shorter deposition time in presence of cationic DTAB. SIEP membranes showed 3–8 times higher H2 permeance compared to that of conventional EP membranes. The SEM, XRD, and EDS studies confirmed the formation of Pd-Ag alloy and no diffusion of MPSS substrate metal components into the Pd-Ag film. The Pd-Ag membrane (15 μm thickness) was tested for long-term stability under thermal cycling (623–723-623 K) up to 42 days.

KW - H separation

KW - H/N selectivity

KW - Pd-Ag membrane

KW - SIEP

KW - thermal stability

UR - https://www.scopus.com/pages/publications/85061906160

U2 - 10.1080/01496395.2019.1576734

DO - 10.1080/01496395.2019.1576734

M3 - Article

SN - 0149-6395

VL - 54

SP - 2084

EP - 2097

JO - Separation Science and Technology (Philadelphia)

JF - Separation Science and Technology (Philadelphia)

IS - 13

ER -

Evaluation and characterization of Pd-Ag composite membrane fabricated by surfactant induced electroless plating (SIEP) for hydrogen separation

Abstract

Keywords

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