First structural determination of a trivalent californium compound with oxygen coordination

Richard E. Sykora; Zerihun Assefa; Richard G. Haire; Thomas E. Albrecht-Schmitt

doi:10.1021/ic051667v

First structural determination of a trivalent californium compound with oxygen coordination

Richard E. Sykora
, Zerihun Assefa
, Richard G. Haire
, Thomas E. Albrecht-Schmitt

Oak Ridge National Laboratory
University of South Alabama
Auburn University

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Single crystals of Cf(IO3)3 (1) were synthesized by the hydrothermal reaction of CfCl3 and H5IO6, and the structure was determined with single-crystal X-ray diffraction. This structural determination of 1 represents the first for a trivalent californium compound containing oxygen coordination. This compound has been further characterized with the use of Raman spectroscopy and emission spectroscopy. Crystallographic data: Cf(IO3)3, monoclinic, space group P21/n, a = 8.7994(10) Å, b = 5.9388(7) Å, c = 15.157(2) Å, β = 96.833(2)°, V = 786.43(16) Å3, Z = 4 (T = 295 K). © 2006 American Chemical Society.

Original language	English
Pages (from-to)	475-477
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	2
DOIs	https://doi.org/10.1021/ic051667v
State	Published - Jan 23 2006

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title = "First structural determination of a trivalent californium compound with oxygen coordination",

abstract = "Single crystals of Cf(IO3)3 (1) were synthesized by the hydrothermal reaction of CfCl3 and H5IO6, and the structure was determined with single-crystal X-ray diffraction. This structural determination of 1 represents the first for a trivalent californium compound containing oxygen coordination. This compound has been further characterized with the use of Raman spectroscopy and emission spectroscopy. Crystallographic data: Cf(IO3)3, monoclinic, space group P21/n, a = 8.7994(10) {\AA}, b = 5.9388(7) {\AA}, c = 15.157(2) {\AA}, β = 96.833(2)°, V = 786.43(16) {\AA}3, Z = 4 (T = 295 K). {\textcopyright} 2006 American Chemical Society.",

author = "Sykora, \{Richard E.\} and Zerihun Assefa and Haire, \{Richard G.\} and Albrecht-Schmitt, \{Thomas E.\}",

year = "2006",

month = jan,

day = "23",

doi = "10.1021/ic051667v",

language = "English",

volume = "45",

pages = "475--477",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - First structural determination of a trivalent californium compound with oxygen coordination

AU - Sykora, Richard E.

AU - Assefa, Zerihun

AU - Haire, Richard G.

AU - Albrecht-Schmitt, Thomas E.

PY - 2006/1/23

Y1 - 2006/1/23

N2 - Single crystals of Cf(IO3)3 (1) were synthesized by the hydrothermal reaction of CfCl3 and H5IO6, and the structure was determined with single-crystal X-ray diffraction. This structural determination of 1 represents the first for a trivalent californium compound containing oxygen coordination. This compound has been further characterized with the use of Raman spectroscopy and emission spectroscopy. Crystallographic data: Cf(IO3)3, monoclinic, space group P21/n, a = 8.7994(10) Å, b = 5.9388(7) Å, c = 15.157(2) Å, β = 96.833(2)°, V = 786.43(16) Å3, Z = 4 (T = 295 K). © 2006 American Chemical Society.

AB - Single crystals of Cf(IO3)3 (1) were synthesized by the hydrothermal reaction of CfCl3 and H5IO6, and the structure was determined with single-crystal X-ray diffraction. This structural determination of 1 represents the first for a trivalent californium compound containing oxygen coordination. This compound has been further characterized with the use of Raman spectroscopy and emission spectroscopy. Crystallographic data: Cf(IO3)3, monoclinic, space group P21/n, a = 8.7994(10) Å, b = 5.9388(7) Å, c = 15.157(2) Å, β = 96.833(2)°, V = 786.43(16) Å3, Z = 4 (T = 295 K). © 2006 American Chemical Society.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 2

ER -

First structural determination of a trivalent californium compound with oxygen coordination

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