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Intramolecular energy transfer in a one-dimensional europium tetracyanoplatinate

  • Branson A. Maynard
  • , Katrina Kalachnikova
  • , Kendra Whitehead
  • , Zerihun Assefa
  • , Richard E. Sykora
  • University of South Alabama
  • North Carolina Agricultural and Technical State University

Research output: Contribution to journalArticlepeer-review

26 Scopus citations

Abstract

The one-dimensional, polymeric compound (C15H11N 3)Eu-(H2O)2(NO3)(Pt(CN) 4)·CH3CN (1) has been shown to display an efficient donor-acceptor intramolecular energy-transfer (IET) process where ligand donors transfer energy to the EuIII acceptor. Single-crystal X-ray diffraction has been used to investigate the structural features of this compound in order to help understand the observed IET process. Crystallographic data: 1, monoclinic, space group P21/c, a = 12.835(1) Å, b = 15.239(1) Å, c = 13.751(2) Å, β = 105.594(9)°, V = 2590.8(5) Å3, and Z = 4 (T = 290 K). © 2008 American Chemical Society.
Original languageEnglish
Pages (from-to)1895-1897
Number of pages3
JournalInorganic Chemistry
Volume47
Issue number6
DOIs
StatePublished - Mar 17 2008

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