Kinetic separation of polymers with different terminals through inclusion complexation with cyclodextrin

Jie Xue; Zhifeng Jia; Xulin Jiang; Yanping Wang; Liang Chen; Li Zhou; Peng He; Xinyuan Zhu; Deyue Yan

doi:10.1021/ma0625152

Kinetic separation of polymers with different terminals through inclusion complexation with cyclodextrin

Jie Xue
, Zhifeng Jia
, Xulin Jiang
, Yanping Wang
, Liang Chen
, Li Zhou
, Peng He
, Xinyuan Zhu
, Deyue Yan

Chemistry

Research output: Contribution to journal › Review article › peer-review

29 Scopus citations

Abstract

A supramolecular end-group separation method based on the complexation kinetics difference between cyclodextrins (CDs) and linear polymers with different terminals, is presented. Cyclodextrins can form the crystalline inclusion complexes with a variety of linear polymers, which readily precipitate from aqueous or organic solvent solution. The molecular recognition between CD and end group of polymeric guest plays a very important role in such complexation. The end-group separation of polymers by supramolecular interaction between CDs and linear polymers with different terminals is found to be reasonable and feasible. This method is an eco-friendly route to separate and purify the linear polymers with identical repeat unit and molecular weight with different end-group functionality, because the host CD is a nontoxic and environmental friendly compound, and can be recycled.

Original language	English
Pages (from-to)	8905-8907
Number of pages	3
Journal	Macromolecules
Volume	39
Issue number	26
DOIs	https://doi.org/10.1021/ma0625152
State	Published - Dec 26 2006

Access to Document

10.1021/ma0625152

Cite this

@article{911b7bf15a294f739fcf682254bb8162,

title = "Kinetic separation of polymers with different terminals through inclusion complexation with cyclodextrin",

abstract = "A supramolecular end-group separation method based on the complexation kinetics difference between cyclodextrins (CDs) and linear polymers with different terminals, is presented. Cyclodextrins can form the crystalline inclusion complexes with a variety of linear polymers, which readily precipitate from aqueous or organic solvent solution. The molecular recognition between CD and end group of polymeric guest plays a very important role in such complexation. The end-group separation of polymers by supramolecular interaction between CDs and linear polymers with different terminals is found to be reasonable and feasible. This method is an eco-friendly route to separate and purify the linear polymers with identical repeat unit and molecular weight with different end-group functionality, because the host CD is a nontoxic and environmental friendly compound, and can be recycled.",

author = "Jie Xue and Zhifeng Jia and Xulin Jiang and Yanping Wang and Liang Chen and Li Zhou and Peng He and Xinyuan Zhu and Deyue Yan",

year = "2006",

month = dec,

day = "26",

doi = "10.1021/ma0625152",

language = "English",

volume = "39",

pages = "8905--8907",

journal = "Macromolecules",

issn = "0024-9297",

number = "26",

}

TY - JOUR

T1 - Kinetic separation of polymers with different terminals through inclusion complexation with cyclodextrin

AU - Xue, Jie

AU - Jia, Zhifeng

AU - Jiang, Xulin

AU - Wang, Yanping

AU - Chen, Liang

AU - Zhou, Li

AU - He, Peng

AU - Zhu, Xinyuan

AU - Yan, Deyue

PY - 2006/12/26

Y1 - 2006/12/26

N2 - A supramolecular end-group separation method based on the complexation kinetics difference between cyclodextrins (CDs) and linear polymers with different terminals, is presented. Cyclodextrins can form the crystalline inclusion complexes with a variety of linear polymers, which readily precipitate from aqueous or organic solvent solution. The molecular recognition between CD and end group of polymeric guest plays a very important role in such complexation. The end-group separation of polymers by supramolecular interaction between CDs and linear polymers with different terminals is found to be reasonable and feasible. This method is an eco-friendly route to separate and purify the linear polymers with identical repeat unit and molecular weight with different end-group functionality, because the host CD is a nontoxic and environmental friendly compound, and can be recycled.

AB - A supramolecular end-group separation method based on the complexation kinetics difference between cyclodextrins (CDs) and linear polymers with different terminals, is presented. Cyclodextrins can form the crystalline inclusion complexes with a variety of linear polymers, which readily precipitate from aqueous or organic solvent solution. The molecular recognition between CD and end group of polymeric guest plays a very important role in such complexation. The end-group separation of polymers by supramolecular interaction between CDs and linear polymers with different terminals is found to be reasonable and feasible. This method is an eco-friendly route to separate and purify the linear polymers with identical repeat unit and molecular weight with different end-group functionality, because the host CD is a nontoxic and environmental friendly compound, and can be recycled.

UR - https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=33846241211&origin=inward

UR - https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=33846241211&origin=inward

U2 - 10.1021/ma0625152

DO - 10.1021/ma0625152

M3 - Review article

SN - 0024-9297

VL - 39

SP - 8905

EP - 8907

JO - Macromolecules

JF - Macromolecules

IS - 26

ER -

Kinetic separation of polymers with different terminals through inclusion complexation with cyclodextrin

Abstract

Access to Document

Other files and links

Fingerprint

Cite this