Photoluminescence and Raman Studies of Curium and Americium Complexes of 6-Methyl 2-(2-Pyridyl)-benzimidazole: Evidence for an Efficient Intramolecular Energy Transfer

Zerihun Assefa; Yaita; Haire; Tachimori

doi:10.1021/ic034759y

Photoluminescence and Raman Studies of Curium and Americium Complexes of 6-Methyl 2-(2-Pyridyl)-benzimidazole: Evidence for an Efficient Intramolecular Energy Transfer

Zerihun Assefa
, Yaita
, Haire
, Tachimori

Chemistry

Oak Ridge National Laboratory
Japan Atomic Energy Agency

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The 6-methyl-2-(2-pyridyl)-benzimidazole (biz) ligand coordinates with the actinide species in solution, and the complexes display efficient intramolecular energy-transfer processes. The energy transfer in the Cm(III) -biz system proceeds in a nonradiative mode, whereas a radiative mode is the principal mechanism in the Am(III)-biz system.

Original language	English
Pages (from-to)	7375-7377
Number of pages	3
Journal	Inorganic Chemistry
Volume	42
Issue number	23
DOIs	https://doi.org/10.1021/ic034759y
State	Published - Nov 17 2003

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title = "Photoluminescence and Raman Studies of Curium and Americium Complexes of 6-Methyl 2-(2-Pyridyl)-benzimidazole: Evidence for an Efficient Intramolecular Energy Transfer",

abstract = "The 6-methyl-2-(2-pyridyl)-benzimidazole (biz) ligand coordinates with the actinide species in solution, and the complexes display efficient intramolecular energy-transfer processes. The energy transfer in the Cm(III) -biz system proceeds in a nonradiative mode, whereas a radiative mode is the principal mechanism in the Am(III)-biz system.",

author = "Zerihun Assefa and Yaita and Haire and Tachimori",

year = "2003",

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T1 - Photoluminescence and Raman Studies of Curium and Americium Complexes of 6-Methyl 2-(2-Pyridyl)-benzimidazole: Evidence for an Efficient Intramolecular Energy Transfer

AU - Assefa, Zerihun

AU - Yaita, null

AU - Haire, null

AU - Tachimori, null

PY - 2003/11/17

Y1 - 2003/11/17

N2 - The 6-methyl-2-(2-pyridyl)-benzimidazole (biz) ligand coordinates with the actinide species in solution, and the complexes display efficient intramolecular energy-transfer processes. The energy transfer in the Cm(III) -biz system proceeds in a nonradiative mode, whereas a radiative mode is the principal mechanism in the Am(III)-biz system.

AB - The 6-methyl-2-(2-pyridyl)-benzimidazole (biz) ligand coordinates with the actinide species in solution, and the complexes display efficient intramolecular energy-transfer processes. The energy transfer in the Cm(III) -biz system proceeds in a nonradiative mode, whereas a radiative mode is the principal mechanism in the Am(III)-biz system.

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U2 - 10.1021/ic034759y

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JF - Inorganic Chemistry

IS - 23

ER -

Photoluminescence and Raman Studies of Curium and Americium Complexes of 6-Methyl 2-(2-Pyridyl)-benzimidazole: Evidence for an Efficient Intramolecular Energy Transfer

Abstract

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