Pulsed laser deposition assisted novel synthesis of self-assembled magnetic nanoparticles

We report here a novel thin film processing method based upon pulsed laser deposition to process nanocrystalline materials with accurate size and interface control with improved magnetic properties. Using this method, single-domain nanocrystalline Fe and Ni particles in the 5-10 nm size range embedded in amorphous alumina as well as in crystalline TiN have been produced. By controlling the size distribution in confined layers, it was possible to tune the magnetic properties from superparamagnetic to ferromagnetic behavior. Magnetic hysteresis characteristics below the blocking temperature are consistent with single-domain behavior. The paper also presents our results from investigations in which scanning transmission electron microscopy with atomic number contrast (STEM-Z) and electron energy loss spectroscopy (EELS) were used to understand the atomic structure of Ni nanoparticles and interface between the nanoparticles and the surrounding matrices. It was interesting to learn from EELS measurements at interfaces of individual grains that Ni in alumina matrix does not form an ionic bond indicating the absence of metal-oxygen bond at the interface. The absence of metal-oxygen bond, in turn, suggests the absence of any dead layer on Ni nanoparticles even in an oxide matrix. © 2003 Elsevier Ltd. All rights reserved.