Self-Assembly of Polymeric Micelles Made of Asymmetric Polystyrene-b-Polyacrylic Acid-b-Polyethylene Oxide for the Synthesis of Mesoporous Nickel Ferrite

Shunsuke Tanaka; Bishnu P Bastakoti; Yunqi Li Shin-ichi Yusa; Daisuke Ishii; Kenya Kani; Amanullah Fatehmulla; Wazirzada Aslam Farooq; Muhammad J. A. Shiddiky; Yoshio Bando; Yusuf Valentino Kaneti; Yusuke Yamauchi; Md. Shahriar A. Hossain

doi:10.1002/ejic.201601459

Self-Assembly of Polymeric Micelles Made of Asymmetric Polystyrene-b-Polyacrylic Acid-b-Polyethylene Oxide for the Synthesis of Mesoporous Nickel Ferrite

Shunsuke Tanaka
, Bishnu P Bastakoti
, Yunqi Li Shin-ichi Yusa
, Daisuke Ishii
, Kenya Kani
, Amanullah Fatehmulla
, Wazirzada Aslam Farooq
, Muhammad J. A. Shiddiky
, Yoshio Bando
, Yusuf Valentino Kaneti
, Yusuke Yamauchi
, Md. Shahriar A. Hossain

Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

In this work, we report the synthesis of mesoporous nickel ferrite with an average pore size of 22 nm by using the laboratory-synthesized asymmetric polystyrene-b-polyacrylic acid-b-polyethylene oxide (PS-b-PAA-b-PEO) triblock copolymer as a soft template. Here, PS acts as a pore-forming agent, whereas PAA acts as a reaction site for the metal ions owing to its strong electrostatic interaction with positively charged metal ions. Furthermore, the PEO polymer provides stability for the micelles in solution and also promotes the orderly organization of the composite particles during assembly of the micelles.

Original language	English
Pages (from-to)	1328-1332
Number of pages	5
Journal	European Journal of Inorganic Chemistry
Volume	2017
Issue number	10
DOIs	https://doi.org/10.1002/ejic.201601459
State	Published - Mar 10 2017

Keywords

Block copolymers
Ferrites
Mesoporous materials
Oxides
Soft-template synthesis

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10.1002/ejic.201601459

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Tanaka, S., Bastakoti, B. P., Yusa, Y. L. S., Ishii, D., Kani, K., Fatehmulla, A., Farooq, W. A., Shiddiky, M. J. A., Bando, Y., Kaneti, Y. V., Yamauchi, Y., & Hossain, M. S. A. (2017). Self-Assembly of Polymeric Micelles Made of Asymmetric Polystyrene-b-Polyacrylic Acid-b-Polyethylene Oxide for the Synthesis of Mesoporous Nickel Ferrite. European Journal of Inorganic Chemistry, 2017(10), 1328-1332. https://doi.org/10.1002/ejic.201601459

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title = "Self-Assembly of Polymeric Micelles Made of Asymmetric Polystyrene-b-Polyacrylic Acid-b-Polyethylene Oxide for the Synthesis of Mesoporous Nickel Ferrite",

abstract = "In this work, we report the synthesis of mesoporous nickel ferrite with an average pore size of 22 nm by using the laboratory-synthesized asymmetric polystyrene-b-polyacrylic acid-b-polyethylene oxide (PS-b-PAA-b-PEO) triblock copolymer as a soft template. Here, PS acts as a pore-forming agent, whereas PAA acts as a reaction site for the metal ions owing to its strong electrostatic interaction with positively charged metal ions. Furthermore, the PEO polymer provides stability for the micelles in solution and also promotes the orderly organization of the composite particles during assembly of the micelles.",

keywords = "Block copolymers, Ferrites, Mesoporous materials, Oxides, Soft-template synthesis",

author = "Shunsuke Tanaka and Bastakoti, \{Bishnu P\} and Yusa, \{Yunqi Li Shin-ichi\} and Daisuke Ishii and Kenya Kani and Amanullah Fatehmulla and Farooq, \{Wazirzada Aslam\} and Shiddiky, \{Muhammad J. A.\} and Yoshio Bando and Kaneti, \{Yusuf Valentino\} and Yusuke Yamauchi and Hossain, \{Md. Shahriar A.\}",

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month = mar,

day = "10",

doi = "10.1002/ejic.201601459",

language = "English",

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journal = "European Journal of Inorganic Chemistry",

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Tanaka, S, Bastakoti, BP, Yusa, YLS, Ishii, D, Kani, K, Fatehmulla, A, Farooq, WA, Shiddiky, MJA, Bando, Y, Kaneti, YV, Yamauchi, Y & Hossain, MSA 2017, 'Self-Assembly of Polymeric Micelles Made of Asymmetric Polystyrene-b-Polyacrylic Acid-b-Polyethylene Oxide for the Synthesis of Mesoporous Nickel Ferrite', European Journal of Inorganic Chemistry, vol. 2017, no. 10, pp. 1328-1332. https://doi.org/10.1002/ejic.201601459

Self-Assembly of Polymeric Micelles Made of Asymmetric Polystyrene-b-Polyacrylic Acid-b-Polyethylene Oxide for the Synthesis of Mesoporous Nickel Ferrite. / Tanaka, Shunsuke; Bastakoti, Bishnu P; Yusa, Yunqi Li Shin-ichi et al.
In: European Journal of Inorganic Chemistry, Vol. 2017, No. 10, 10.03.2017, p. 1328-1332.

Research output: Contribution to journal › Article › peer-review

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T1 - Self-Assembly of Polymeric Micelles Made of Asymmetric Polystyrene-b-Polyacrylic Acid-b-Polyethylene Oxide for the Synthesis of Mesoporous Nickel Ferrite

AU - Tanaka, Shunsuke

AU - Bastakoti, Bishnu P

AU - Yusa, Yunqi Li Shin-ichi

AU - Ishii, Daisuke

AU - Kani, Kenya

AU - Fatehmulla, Amanullah

AU - Farooq, Wazirzada Aslam

AU - Shiddiky, Muhammad J. A.

AU - Bando, Yoshio

AU - Kaneti, Yusuf Valentino

AU - Yamauchi, Yusuke

AU - Hossain, Md. Shahriar A.

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N2 - In this work, we report the synthesis of mesoporous nickel ferrite with an average pore size of 22 nm by using the laboratory-synthesized asymmetric polystyrene-b-polyacrylic acid-b-polyethylene oxide (PS-b-PAA-b-PEO) triblock copolymer as a soft template. Here, PS acts as a pore-forming agent, whereas PAA acts as a reaction site for the metal ions owing to its strong electrostatic interaction with positively charged metal ions. Furthermore, the PEO polymer provides stability for the micelles in solution and also promotes the orderly organization of the composite particles during assembly of the micelles.

AB - In this work, we report the synthesis of mesoporous nickel ferrite with an average pore size of 22 nm by using the laboratory-synthesized asymmetric polystyrene-b-polyacrylic acid-b-polyethylene oxide (PS-b-PAA-b-PEO) triblock copolymer as a soft template. Here, PS acts as a pore-forming agent, whereas PAA acts as a reaction site for the metal ions owing to its strong electrostatic interaction with positively charged metal ions. Furthermore, the PEO polymer provides stability for the micelles in solution and also promotes the orderly organization of the composite particles during assembly of the micelles.

KW - Block copolymers

KW - Ferrites

KW - Mesoporous materials

KW - Oxides

KW - Soft-template synthesis

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 10

ER -

Self-Assembly of Polymeric Micelles Made of Asymmetric Polystyrene-b-Polyacrylic Acid-b-Polyethylene Oxide for the Synthesis of Mesoporous Nickel Ferrite

Abstract

Keywords

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