Abstract
The synthesis of fac-tris(trimethylphosphine)iridiumtrichloride is reported and the crystal structure of five different solvates of this compound are analyzed. Compared with the idealized structure calculated with DFT methods, bond angles and distances differ considerably for all of the solvates examined. The utility of fac-tris(trimethylphosphine)iridiumtrichloride for the synthesis of organometallic compounds of iridium(III) is also demonstrated. © 2013 Elsevier Ltd. All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 67-73 |
| Number of pages | 7 |
| Journal | Polyhedron |
| Volume | 54 |
| Issue number | 30 |
| DOIs | |
| State | Published - Apr 30 2013 |
Keywords
- Crystal packing forces
- Iridium chloride complexes
- Iridium complex isomers
- Iridium phosphine chlorides
- Phosphine iridium complexes
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