Tri-2-furyl-phosphine oxide: An oxidation product of the weak Lewis base tri-2-furylphosphine

Darkus Jenkins; Richard E. Sykora; Zerihun Assefa

doi:10.1107/S1600536807034125

Tri-2-furyl-phosphine oxide: An oxidation product of the weak Lewis base tri-2-furylphosphine

Darkus Jenkins
, Richard E. Sykora
, Zerihun Assefa

North Carolina Agricultural and Technical State University
University of South Alabama

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The title compound, C12H9O4P, was prepared by the oxidation of tri-2-furylphosphine. The P=O bond length is 1.478 (2) Å and the C - P bond lengths range from 1.774 (2) to 1.785 (2) Å. The tri-2-furyl- phosphine oxide molecule displays a very distorted confirmation (not propeller-like) due to the large variation in O - P - C - C torsion angles [5.6 (3), 8.5 (3) and 118.0 (3)°]. The crystal structure involves intermolecular C - H⋯O hydrogen bonds. © International Union of Crystallography 2007.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	8
DOIs	https://doi.org/10.1107/S1600536807034125
State	Published - Jul 31 2007

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title = "Tri-2-furyl-phosphine oxide: An oxidation product of the weak Lewis base tri-2-furylphosphine",

abstract = "The title compound, C12H9O4P, was prepared by the oxidation of tri-2-furylphosphine. The P=O bond length is 1.478 (2) {\AA} and the C - P bond lengths range from 1.774 (2) to 1.785 (2) {\AA}. The tri-2-furyl- phosphine oxide molecule displays a very distorted confirmation (not propeller-like) due to the large variation in O - P - C - C torsion angles [5.6 (3), 8.5 (3) and 118.0 (3)°]. The crystal structure involves intermolecular C - H⋯O hydrogen bonds. {\textcopyright} International Union of Crystallography 2007.",

author = "Darkus Jenkins and Sykora, \{Richard E.\} and Zerihun Assefa",

year = "2007",

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doi = "10.1107/S1600536807034125",

language = "English",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Tri-2-furyl-phosphine oxide: An oxidation product of the weak Lewis base tri-2-furylphosphine

AU - Jenkins, Darkus

AU - Sykora, Richard E.

AU - Assefa, Zerihun

PY - 2007/7/31

Y1 - 2007/7/31

N2 - The title compound, C12H9O4P, was prepared by the oxidation of tri-2-furylphosphine. The P=O bond length is 1.478 (2) Å and the C - P bond lengths range from 1.774 (2) to 1.785 (2) Å. The tri-2-furyl- phosphine oxide molecule displays a very distorted confirmation (not propeller-like) due to the large variation in O - P - C - C torsion angles [5.6 (3), 8.5 (3) and 118.0 (3)°]. The crystal structure involves intermolecular C - H⋯O hydrogen bonds. © International Union of Crystallography 2007.

AB - The title compound, C12H9O4P, was prepared by the oxidation of tri-2-furylphosphine. The P=O bond length is 1.478 (2) Å and the C - P bond lengths range from 1.774 (2) to 1.785 (2) Å. The tri-2-furyl- phosphine oxide molecule displays a very distorted confirmation (not propeller-like) due to the large variation in O - P - C - C torsion angles [5.6 (3), 8.5 (3) and 118.0 (3)°]. The crystal structure involves intermolecular C - H⋯O hydrogen bonds. © International Union of Crystallography 2007.

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DO - 10.1107/S1600536807034125

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SN - 1600-5368

VL - 63

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Tri-2-furyl-phosphine oxide: An oxidation product of the weak Lewis base tri-2-furylphosphine

Abstract

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